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2 Dec 2025

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Understanding Intermolecular Forces for AQA Chemistry

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hammerbro @hammerbro

Ever wonder why water boils at 100°C whilst other similar molecules boil at much lower temperatures? It's all... Show more

Intermolecular Forces - AQA A-Level Chemistry.

Intermolecular forces are forces between molecules tohold them together
They are very weak-m

Understanding Intermolecular Forces

Think of intermolecular forces as the "glue" that holds molecules together, though they're much weaker than the bonds within molecules themselves. These forces might be weak, but they're absolutely crucial for determining how substances behave in the real world.

There are three main types you need to know Van der Waals forces (the weakest), permanent dipole-dipole interactions (medium strength), and hydrogen bonding (the strongest). Each one works differently and affects substances in unique ways.

Van der Waals forces are the most basic type - they exist between all molecules and even noble gas atoms. As molecules get larger, these forces become stronger because there's more surface area for attraction. This explains why helium boils at -269°C whilst xenon boils at -108°C.

Quick Check Remember that molecular size directly affects Van der Waals forces - bigger molecules = stronger forces = higher boiling points!

Intermolecular Forces - AQA A-Level Chemistry.

Intermolecular forces are forces between molecules tohold them together
They are very weak-m

Dipole Interactions and Hydrogen Bonding

Permanent dipole-dipole interactions occur when molecules have uneven charge distribution due to differences in electronegativity. Picture HCl molecules lining up so the slightly positive hydrogen end attracts the slightly negative chlorine end of neighbouring molecules.

Hydrogen bonding takes this concept further and creates the strongest intermolecular force. It only happens when hydrogen is bonded to fluorine, oxygen, or nitrogen - the three most electronegative elements. The hydrogen's positive charge attracts lone pairs of electrons on these atoms.

Water perfectly demonstrates hydrogen bonding in action. These special bonds give water its unique properties ice is less dense than liquid water (creating the lattice structure that makes ice float), water has an unusually high boiling point, and it shows remarkable surface tension.

Real-World Connection Without hydrogen bonding, water would boil at around -80°C, making life on Earth impossible!

Intermolecular Forces - AQA A-Level Chemistry.

Intermolecular forces are forces between molecules tohold them together
They are very weak-m

Patterns in Hydrides and Key Rules

Looking at hydrides (compounds of hydrogen with other elements) reveals fascinating patterns. In Groups 5, 6, and 7, the first member always has a much higher boiling point than expected - NH₃, H₂O, and HF all break the trend because of hydrogen bonding.

For other hydrides moving down each group, two competing factors battle it out. Polarity decreases (weakening dipole forces) whilst molecular size increases (strengthening Van der Waals forces). The size effect usually wins, explaining why H₂Te boils higher than H₂S.

Here are the essential rules you need to remember all molecules have Van der Waals forces as a baseline, polar molecules add dipole-dipole forces on top, and hydrogen bonding only occurs with F, O, or N. These forces directly determine physical properties like boiling points, melting points, and solubility.

Exam Tip When predicting boiling points, first check for hydrogen bonding, then consider molecular size and polarity - this approach works every time!

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Chemistry

169

2 Dec 2025

3 pages

Understanding Intermolecular Forces for AQA Chemistry

user profile picture

hammerbro

@hammerbro

Ever wonder why water boils at 100°C whilst other similar molecules boil at much lower temperatures? It's all down to intermolecular forces - the invisible attractions between molecules that determine how substances behave. Understanding these forces will help you predict... Show more

Intermolecular Forces - AQA A-Level Chemistry.

Intermolecular forces are forces between molecules tohold them together
They are very weak-m

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Understanding Intermolecular Forces

Think of intermolecular forces as the "glue" that holds molecules together, though they're much weaker than the bonds within molecules themselves. These forces might be weak, but they're absolutely crucial for determining how substances behave in the real world.

There are three main types you need to know: Van der Waals forces (the weakest), permanent dipole-dipole interactions (medium strength), and hydrogen bonding (the strongest). Each one works differently and affects substances in unique ways.

Van der Waals forces are the most basic type - they exist between all molecules and even noble gas atoms. As molecules get larger, these forces become stronger because there's more surface area for attraction. This explains why helium boils at -269°C whilst xenon boils at -108°C.

Quick Check: Remember that molecular size directly affects Van der Waals forces - bigger molecules = stronger forces = higher boiling points!

Intermolecular Forces - AQA A-Level Chemistry.

Intermolecular forces are forces between molecules tohold them together
They are very weak-m

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Dipole Interactions and Hydrogen Bonding

Permanent dipole-dipole interactions occur when molecules have uneven charge distribution due to differences in electronegativity. Picture HCl molecules lining up so the slightly positive hydrogen end attracts the slightly negative chlorine end of neighbouring molecules.

Hydrogen bonding takes this concept further and creates the strongest intermolecular force. It only happens when hydrogen is bonded to fluorine, oxygen, or nitrogen - the three most electronegative elements. The hydrogen's positive charge attracts lone pairs of electrons on these atoms.

Water perfectly demonstrates hydrogen bonding in action. These special bonds give water its unique properties: ice is less dense than liquid water (creating the lattice structure that makes ice float), water has an unusually high boiling point, and it shows remarkable surface tension.

Real-World Connection: Without hydrogen bonding, water would boil at around -80°C, making life on Earth impossible!

Intermolecular Forces - AQA A-Level Chemistry.

Intermolecular forces are forces between molecules tohold them together
They are very weak-m

Sign up to see the contentIt's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Patterns in Hydrides and Key Rules

Looking at hydrides (compounds of hydrogen with other elements) reveals fascinating patterns. In Groups 5, 6, and 7, the first member always has a much higher boiling point than expected - NH₃, H₂O, and HF all break the trend because of hydrogen bonding.

For other hydrides moving down each group, two competing factors battle it out. Polarity decreases (weakening dipole forces) whilst molecular size increases (strengthening Van der Waals forces). The size effect usually wins, explaining why H₂Te boils higher than H₂S.

Here are the essential rules you need to remember: all molecules have Van der Waals forces as a baseline, polar molecules add dipole-dipole forces on top, and hydrogen bonding only occurs with F, O, or N. These forces directly determine physical properties like boiling points, melting points, and solubility.

Exam Tip: When predicting boiling points, first check for hydrogen bonding, then consider molecular size and polarity - this approach works every time!

We thought you’d never ask...

What is the Knowunity AI companion?

Our AI Companion is a student-focused AI tool that offers more than just answers. Built on millions of Knowunity resources, it provides relevant information, personalised study plans, quizzes, and content directly in the chat, adapting to your individual learning journey.

Where can I download the Knowunity app?

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Is Knowunity really free of charge?

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Stefan S

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This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.

Samantha Klich

Android user

Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.

Anna

iOS user

Best app on earth! no words because it’s too good

Thomas R

iOS user

Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.

Basil

Android user

This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.

David K

iOS user

The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!

Sudenaz Ocak

Android user

In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.

Greenlight Bonnie

Android user

very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.

Rohan U

Android user

I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didn’t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as I’m sure you too will see developments.

Xander S

iOS user

THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮

Elisha

iOS user

This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now

Paul T

iOS user

The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.

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iOS user

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Samantha Klich

Android user

Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.

Anna

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Best app on earth! no words because it’s too good

Thomas R

iOS user

Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.

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David K

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The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!

Sudenaz Ocak

Android user

In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.

Greenlight Bonnie

Android user

very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.

Rohan U

Android user

I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didn’t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as I’m sure you too will see developments.

Xander S

iOS user

THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮

Elisha

iOS user

This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now

Paul T

iOS user