Patterns in Hydrides and Key Rules
Looking at hydrides (compounds of hydrogen with other elements) reveals fascinating patterns. In Groups 5, 6, and 7, the first member always has a much higher boiling point than expected - NH₃, H₂O, and HF all break the trend because of hydrogen bonding.
For other hydrides moving down each group, two competing factors battle it out. Polarity decreases (weakening dipole forces) whilst molecular size increases (strengthening Van der Waals forces). The size effect usually wins, explaining why H₂Te boils higher than H₂S.
Here are the essential rules you need to remember: all molecules have Van der Waals forces as a baseline, polar molecules add dipole-dipole forces on top, and hydrogen bonding only occurs with F, O, or N. These forces directly determine physical properties like boiling points, melting points, and solubility.
Exam Tip: When predicting boiling points, first check for hydrogen bonding, then consider molecular size and polarity - this approach works every time!