Permanent Dipole-Permanent Dipole Interactions
Polar molecules have permanent dipoles โ regions of partial positive and negative charge that don't shift over time. When these molecules encounter each other, the positive end of one molecule attracts the negative end of another, creating permanent dipole-permanent dipole interactions.
These interactions are stronger than London Dispersion forces when comparing molecules with similar numbers of electrons. You'll find them in molecules with certain shapes: linear, angular, and trigonal pyramidal compounds containing polar bonds will be polar overall.
Molecular shape determines whether a molecule is polar. For example, tetrahedral molecules with four identical groups around the central atom (like CClโ) are non-polar despite having polar bonds, because the bond dipoles cancel out. However, if one group differs (like in CHClโ), the molecule becomes polar.
Quick tip: To determine if permanent dipole interactions will occur, first check if the molecule has polar bonds, then analyze its shape to see if those bond dipoles create an overall molecular dipole.