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Fun with Alcohols: How They Change and Their Cool Properties!

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ziyah

19/10/2025

Chemistry

Organic Chemistry: Alcohols

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19 Oct 2025

โ€ข

2 pages

Fun with Alcohols: How They Change and Their Cool Properties!

user profile picture

ziyah

@ziy4h

Hey there! Ever wondered how alcohols change with stuff like KMnO4 and K2Cr2O7? Weโ€™ll explore fun experiments, talk about primary, secondary, and tertiary alcohols, and their awesome physical and chemical properties! Come join the science fun! ๐ŸŒŸ

# ALCOHOLS

Primary Tertiary

> PREVIOUS KNOWLEDGE:

Secondary

โ€ข Alcohols form a homolous series that

OH OH
are saturated, containing only

Oxidation of Alcohols

The oxidation of alcohols is a fundamental reaction in organic chemistry, with important applications in industry and biochemistry. This page explores the oxidation reactions of different classes of alcohols and their products.

Definition: Oxidation of alcohols involves the loss of hydrogen atoms or the gain of oxygen atoms, resulting in the formation of aldehydes, ketones, or carboxylic acids.

Combustion of Alcohols: Alcohols can undergo complete combustion, serving as fuels to release stored chemical energy:

Example: Cโ‚‚Hโ‚…OHll + 3Oโ‚‚ โ†’ 2COโ‚‚ + 3Hโ‚‚O

This reaction demonstrates the use of alcohols as alternative fuel sources.

Oxidation Reactions: The oxidation of alcohols depends on their classification:

  1. Primary Alcohols:

    • Gentle heating: Produces aldehydes
    • Stronger heating under reflux with excess oxidizing agent: Produces carboxylic acids
  2. Secondary Alcohols:

    • Heating under reflux: Produces ketones
  3. Tertiary Alcohols:

    • Resistant to oxidation by common oxidizing agents

Highlight: The oxidation of primary and secondary alcohols is easily observed by a color change from orange to green when using acidified potassium dichromate(VI) as the oxidizing agent.

Oxidation Mechanism: The oxidation of alcohols mechanism typically involves the use of strong oxidizing agents such as potassium permanganate (KMnOโ‚„) or potassium dichromate (Kโ‚‚Crโ‚‚Oโ‚‡). The reaction proceeds through the following steps:

  1. Formation of a chromate ester intermediate
  2. Elimination of HCrOโ‚ƒโป to form a carbonyl compound
  3. Further oxidation of aldehydes to carboxylic acids (in the case of primary alcohols)

Vocabulary: Reflux is a technique used in chemistry to heat a reaction mixture for an extended period while continuously cooling and returning vaporized reactants to the reaction vessel.

Understanding the oxidation of alcohols experiment and mechanism is crucial for organic synthesis and the production of important industrial chemicals. The ability to predict and control these reactions is a key skill in organic chemistry.

# ALCOHOLS

Primary Tertiary

> PREVIOUS KNOWLEDGE:

Secondary

โ€ข Alcohols form a homolous series that

OH OH
are saturated, containing only

Classification and Properties of Alcohols

Alcohols are an important class of organic compounds with diverse applications. This page introduces the fundamental concepts of alcohol classification and their key physical properties.

Definition: Alcohols are organic compounds containing a hydroxyl โˆ’OH-OH group attached to a carbon atom.

The classification of alcohols is based on the type of carbon atom to which the hydroxyl group is attached:

Highlight: Alcohols are classified as primary, secondary, or tertiary based on the number of carbon atoms directly bonded to the carbon bearing the -OH group.

  1. Primary alcohols: The -OH group is attached to a carbon atom bonded to one other carbon atom.

    Example: Propan-1-ol (CHโ‚ƒCHโ‚‚CHโ‚‚OH)

  2. Secondary alcohols: The -OH group is attached to a carbon atom bonded to two other carbon atoms.

    Example: Propan-2-ol (CHโ‚ƒCH(OH)CHโ‚ƒ)

  3. Tertiary alcohols: The -OH group is attached to a carbon atom bonded to three other carbon atoms.

    Example: 2-methyl propan-2-ol ((CHโ‚ƒ)โ‚ƒCOH)

The physical properties of alcohols are significantly influenced by their ability to form hydrogen bonds:

Vocabulary: Hydrogen bonding is a strong intermolecular force between a hydrogen atom bonded to a highly electronegative atom (like oxygen) and another electronegative atom.

  1. Volatility: Alcohols are less volatile than corresponding alkanes due to hydrogen bonding.

  2. Solubility: The polar -OH group allows smaller alcohols to be soluble in water. Solubility decreases as the alkyl chain length increases.

  3. Boiling points: Alcohols have higher boiling points than alkanes of similar molecular mass due to hydrogen bonding.

Highlight: The boiling points of alcohols increase as the chain length increases due to stronger induced dipole-dipole intermolecular forces.

Understanding these properties is crucial for predicting the behavior of alcohols in various chemical reactions and applications.



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The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.

Stefan S

iOS user

This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.

Samantha Klich

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Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.

Anna

iOS user

Best app on earth! no words because itโ€™s too good

Thomas R

iOS user

Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.

Basil

Android user

This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.

David K

iOS user

The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!

Sudenaz Ocak

Android user

In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.

Greenlight Bonnie

Android user

very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.

Rohan U

Android user

I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didnโ€™t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as Iโ€™m sure you too will see developments.

Xander S

iOS user

THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH ๐Ÿ˜๐Ÿ˜๐Ÿ˜ฒ๐Ÿค‘๐Ÿ’—โœจ๐ŸŽ€๐Ÿ˜ฎ

Elisha

iOS user

This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now

Paul T

iOS user

The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.

Stefan S

iOS user

This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.

Samantha Klich

Android user

Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.

Anna

iOS user

Best app on earth! no words because itโ€™s too good

Thomas R

iOS user

Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.

Basil

Android user

This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.

David K

iOS user

The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!

Sudenaz Ocak

Android user

In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.

Greenlight Bonnie

Android user

very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.

Rohan U

Android user

I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didnโ€™t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as Iโ€™m sure you too will see developments.

Xander S

iOS user

THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH ๐Ÿ˜๐Ÿ˜๐Ÿ˜ฒ๐Ÿค‘๐Ÿ’—โœจ๐ŸŽ€๐Ÿ˜ฎ

Elisha

iOS user

This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now

Paul T

iOS user

ย 

Chemistry

โ€ข

1,617

โ€ข

19 Oct 2025

โ€ข

2 pages

Fun with Alcohols: How They Change and Their Cool Properties!

user profile picture

ziyah

@ziy4h

Hey there! Ever wondered how alcohols change with stuff like KMnO4 and K2Cr2O7? Weโ€™ll explore fun experiments, talk about primary, secondary, and tertiary alcohols, and their awesome physical and chemical properties! Come join the science fun! ๐ŸŒŸ

# ALCOHOLS

Primary Tertiary

> PREVIOUS KNOWLEDGE:

Secondary

โ€ข Alcohols form a homolous series that

OH OH
are saturated, containing only

Sign up to see the contentIt's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Oxidation of Alcohols

The oxidation of alcohols is a fundamental reaction in organic chemistry, with important applications in industry and biochemistry. This page explores the oxidation reactions of different classes of alcohols and their products.

Definition: Oxidation of alcohols involves the loss of hydrogen atoms or the gain of oxygen atoms, resulting in the formation of aldehydes, ketones, or carboxylic acids.

Combustion of Alcohols: Alcohols can undergo complete combustion, serving as fuels to release stored chemical energy:

Example: Cโ‚‚Hโ‚…OHll + 3Oโ‚‚ โ†’ 2COโ‚‚ + 3Hโ‚‚O

This reaction demonstrates the use of alcohols as alternative fuel sources.

Oxidation Reactions: The oxidation of alcohols depends on their classification:

  1. Primary Alcohols:

    • Gentle heating: Produces aldehydes
    • Stronger heating under reflux with excess oxidizing agent: Produces carboxylic acids
  2. Secondary Alcohols:

    • Heating under reflux: Produces ketones
  3. Tertiary Alcohols:

    • Resistant to oxidation by common oxidizing agents

Highlight: The oxidation of primary and secondary alcohols is easily observed by a color change from orange to green when using acidified potassium dichromate(VI) as the oxidizing agent.

Oxidation Mechanism: The oxidation of alcohols mechanism typically involves the use of strong oxidizing agents such as potassium permanganate (KMnOโ‚„) or potassium dichromate (Kโ‚‚Crโ‚‚Oโ‚‡). The reaction proceeds through the following steps:

  1. Formation of a chromate ester intermediate
  2. Elimination of HCrOโ‚ƒโป to form a carbonyl compound
  3. Further oxidation of aldehydes to carboxylic acids (in the case of primary alcohols)

Vocabulary: Reflux is a technique used in chemistry to heat a reaction mixture for an extended period while continuously cooling and returning vaporized reactants to the reaction vessel.

Understanding the oxidation of alcohols experiment and mechanism is crucial for organic synthesis and the production of important industrial chemicals. The ability to predict and control these reactions is a key skill in organic chemistry.

# ALCOHOLS

Primary Tertiary

> PREVIOUS KNOWLEDGE:

Secondary

โ€ข Alcohols form a homolous series that

OH OH
are saturated, containing only

Sign up to see the contentIt's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Classification and Properties of Alcohols

Alcohols are an important class of organic compounds with diverse applications. This page introduces the fundamental concepts of alcohol classification and their key physical properties.

Definition: Alcohols are organic compounds containing a hydroxyl โˆ’OH-OH group attached to a carbon atom.

The classification of alcohols is based on the type of carbon atom to which the hydroxyl group is attached:

Highlight: Alcohols are classified as primary, secondary, or tertiary based on the number of carbon atoms directly bonded to the carbon bearing the -OH group.

  1. Primary alcohols: The -OH group is attached to a carbon atom bonded to one other carbon atom.

    Example: Propan-1-ol (CHโ‚ƒCHโ‚‚CHโ‚‚OH)

  2. Secondary alcohols: The -OH group is attached to a carbon atom bonded to two other carbon atoms.

    Example: Propan-2-ol (CHโ‚ƒCH(OH)CHโ‚ƒ)

  3. Tertiary alcohols: The -OH group is attached to a carbon atom bonded to three other carbon atoms.

    Example: 2-methyl propan-2-ol ((CHโ‚ƒ)โ‚ƒCOH)

The physical properties of alcohols are significantly influenced by their ability to form hydrogen bonds:

Vocabulary: Hydrogen bonding is a strong intermolecular force between a hydrogen atom bonded to a highly electronegative atom (like oxygen) and another electronegative atom.

  1. Volatility: Alcohols are less volatile than corresponding alkanes due to hydrogen bonding.

  2. Solubility: The polar -OH group allows smaller alcohols to be soluble in water. Solubility decreases as the alkyl chain length increases.

  3. Boiling points: Alcohols have higher boiling points than alkanes of similar molecular mass due to hydrogen bonding.

Highlight: The boiling points of alcohols increase as the chain length increases due to stronger induced dipole-dipole intermolecular forces.

Understanding these properties is crucial for predicting the behavior of alcohols in various chemical reactions and applications.

We thought youโ€™d never ask...

What is the Knowunity AI companion?

Our AI Companion is a student-focused AI tool that offers more than just answers. Built on millions of Knowunity resources, it provides relevant information, personalised study plans, quizzes, and content directly in the chat, adapting to your individual learning journey.

Where can I download the Knowunity app?

You can download the app from Google Play Store and Apple App Store.

Is Knowunity really free of charge?

That's right! Enjoy free access to study content, connect with fellow students, and get instant help โ€“ all at your fingertips.

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4.9/5

App Store

4.8/5

Google Play

The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.

Stefan S

iOS user

This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.

Samantha Klich

Android user

Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.

Anna

iOS user

Best app on earth! no words because itโ€™s too good

Thomas R

iOS user

Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.

Basil

Android user

This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.

David K

iOS user

The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!

Sudenaz Ocak

Android user

In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.

Greenlight Bonnie

Android user

very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.

Rohan U

Android user

I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didnโ€™t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as Iโ€™m sure you too will see developments.

Xander S

iOS user

THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH ๐Ÿ˜๐Ÿ˜๐Ÿ˜ฒ๐Ÿค‘๐Ÿ’—โœจ๐ŸŽ€๐Ÿ˜ฎ

Elisha

iOS user

This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now

Paul T

iOS user

The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.

Stefan S

iOS user

This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.

Samantha Klich

Android user

Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.

Anna

iOS user

Best app on earth! no words because itโ€™s too good

Thomas R

iOS user

Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.

Basil

Android user

This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.

David K

iOS user

The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!

Sudenaz Ocak

Android user

In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.

Greenlight Bonnie

Android user

very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.

Rohan U

Android user

I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didnโ€™t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as Iโ€™m sure you too will see developments.

Xander S

iOS user

THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH ๐Ÿ˜๐Ÿ˜๐Ÿ˜ฒ๐Ÿค‘๐Ÿ’—โœจ๐ŸŽ€๐Ÿ˜ฎ

Elisha

iOS user

This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now

Paul T

iOS user