Elimination Reactions and Environmental Impact
Sometimes halogenoalkanes don't substitute - they eliminate instead! Under high temperature with alcoholic conditions, nucleophiles act as bases rather than substitution agents. They grab a hydrogen atom, forcing the molecule to form a carbon-carbon double bond and create an alkene.
This elimination mechanism only occurs with secondary and tertiary halogenoalkanes. The base removes a proton whilst the halogen leaves, resulting in a new double bond formation.
But here's the environmental twist - halogenoalkanes like CFCs are seriously damaging our ozone layer. When UV radiation breaks their carbon-halogen bonds, free radicals form that catalyse ozone destruction. Just one chlorine radical can destroy thousands of ozone molecules!
Thankfully, CFC-free solvents are now being developed to prevent atmospheric damage. This shift helps minimise both ozone depletion and global warming - showing how chemistry directly impacts environmental protection.
Environmental Alert: The same UV absorption that makes CFCs useful also makes them incredibly destructive to our protective ozone layer.