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2 Jan 2026

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2 pages

Halogenoalkanes: Chemistry Notes

Poppy Sykes

@poppy_sykes

Halogenealkanes are organic compounds where hydrogen atoms in alkanes have... Show more

# Halogenealkanes

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> nucleophilic subohtution

Ls elemeination reactions

## Key Words

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halogenealkans

Formation and Properties of Halogenealkanes

Ever wondered how chemists create the building blocks for everything from medicines to plastics? Halogenealkanes are your answer - they're like the Swiss Army knife of organic chemistry!

You can make halogenealkanes in several ways. The most common method is free radical substitution of alkanes, where UV light helps chlorine atoms replace hydrogen atoms. You can also use electrophilic addition - for example, adding HBr to ethene gives you bromoethane $C₂H₄ + HBr → CH₃CH₂Br$ .

Another brilliant method involves treating alcohols with hydrogen halides. Want a chloroalkane? Treat your alcohol with PCl₅ or concentrated H₂SO₄ with KCl. For bromoalkanes, use 50% sulphuric acid with potassium bromide. Iodoalkanes are trickier since H₂SO₄ would oxidise the hydrogen iodide, so chemists use red phosphorus with iodine instead.

💡 Quick Tip: The rate of reaction with nucleophiles follows this pattern: iodo > bromo > chloro > fluoro. This happens because iodine forms the weakest C-halogen bond (largest atomic radius), whilst fluorine forms the strongest bond (smallest atomic radius).

Nucleophilic Substitution and Elimination Reactions

Here's where halogenealkanes really shine - they're incredibly versatile in reactions, and understanding these mechanisms will make organic chemistry so much clearer!

Nucleophilic substitution occurs when the halogen atom gets replaced by a nucleophile (something with a lone pair to donate). There are two main mechanisms: SN1 involves forming a carbocation intermediate (tertiary halogenealkanes love this route), whilst SN2 happens in one step with both the nucleophile attacking and the halogen leaving simultaneously (primary halogenealkanes prefer this).

You can create loads of useful compounds this way. Treat with aqueous NaOH under reflux to get alcohols, use potassium cyanide in ethanol to make nitriles (brilliant for extending carbon chains), or react with concentrated ammonia to form amines.

Elimination reactions are equally important - heat a halogenealkane with concentrated NaOH in ethanol, and you'll get an alkene plus water. Whether you get substitution or elimination depends on your conditions: aqueous solutions and lower temperatures favour substitution, whilst ethanolic solutions and higher temperatures push towards elimination.

💡 Remember: Primary halogenealkanes mainly undergo SN2 and substitution, tertiary ones prefer SN1 and elimination, whilst secondary ones can do both - it's all about stability!

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Chemistry

•

2 Jan 2026

•

2 pages

Halogenoalkanes: Chemistry Notes

Poppy Sykes

@poppy_sykes

Halogenealkanes are organic compounds where hydrogen atoms in alkanes have been replaced by halogen atoms (fluorine, chlorine, bromine, or iodine). These compounds are incredibly useful in chemical synthesis because they can undergo two main types of reactions - nucleophilic substitution... Show more

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Formation and Properties of Halogenealkanes

Ever wondered how chemists create the building blocks for everything from medicines to plastics? Halogenealkanes are your answer - they're like the Swiss Army knife of organic chemistry!

💡 Quick Tip: The rate of reaction with nucleophiles follows this pattern: iodo > bromo > chloro > fluoro. This happens because iodine forms the weakest C-halogen bond (largest atomic radius), whilst fluorine forms the strongest bond (smallest atomic radius).

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Nucleophilic Substitution and Elimination Reactions

Here's where halogenealkanes really shine - they're incredibly versatile in reactions, and understanding these mechanisms will make organic chemistry so much clearer!

💡 Remember: Primary halogenealkanes mainly undergo SN2 and substitution, tertiary ones prefer SN1 and elimination, whilst secondary ones can do both - it's all about stability!