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Chemistry
11 Dec 2025
52
2 pages
Poppy Sykes @poppy_sykes
Halogenealkanes are organic compounds where hydrogen atoms in alkanes have been replaced by halogen atoms (fluorine, chlorine, bromine,... Show more
Ever wondered how chemists create the building blocks for everything from medicines to plastics? Halogenealkanes are your answer - they're like the Swiss Army knife of organic chemistry!
You can make halogenealkanes in several ways. The most common method is free radical substitution of alkanes, where UV light helps chlorine atoms replace hydrogen atoms. You can also use electrophilic addition - for example, adding HBr to ethene gives you bromoethane .
Another brilliant method involves treating alcohols with hydrogen halides. Want a chloroalkane? Treat your alcohol with PCl₅ or concentrated H₂SO₄ with KCl. For bromoalkanes, use 50% sulphuric acid with potassium bromide. Iodoalkanes are trickier since H₂SO₄ would oxidise the hydrogen iodide, so chemists use red phosphorus with iodine instead.
💡 Quick Tip The rate of reaction with nucleophiles follows this pattern iodo > bromo > chloro > fluoro. This happens because iodine forms the weakest C-halogen bond (largest atomic radius), whilst fluorine forms the strongest bond (smallest atomic radius).
Here's where halogenealkanes really shine - they're incredibly versatile in reactions, and understanding these mechanisms will make organic chemistry so much clearer!
Nucleophilic substitution occurs when the halogen atom gets replaced by a nucleophile (something with a lone pair to donate). There are two main mechanisms SN1 involves forming a carbocation intermediate (tertiary halogenealkanes love this route), whilst SN2 happens in one step with both the nucleophile attacking and the halogen leaving simultaneously (primary halogenealkanes prefer this).
You can create loads of useful compounds this way. Treat with aqueous NaOH under reflux to get alcohols, use potassium cyanide in ethanol to make nitriles (brilliant for extending carbon chains), or react with concentrated ammonia to form amines.
Elimination reactions are equally important - heat a halogenealkane with concentrated NaOH in ethanol, and you'll get an alkene plus water. Whether you get substitution or elimination depends on your conditions aqueous solutions and lower temperatures favour substitution, whilst ethanolic solutions and higher temperatures push towards elimination.
💡 Remember Primary halogenealkanes mainly undergo SN2 and substitution, tertiary ones prefer SN1 and elimination, whilst secondary ones can do both - it's all about stability!
Our AI Companion is a student-focused AI tool that offers more than just answers. Built on millions of Knowunity resources, it provides relevant information, personalised study plans, quizzes, and content directly in the chat, adapting to your individual learning journey.
You can download the app from Google Play Store and Apple App Store.
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Explore key organic reaction mechanisms including electrophilic addition, electrophilic substitution, and nucleophilic substitution. This summary covers the reactions of alkenes, benzene, carbonyl compounds, and halogenoalkanes, detailing reactants, products, and conditions necessary for each mechanism. Ideal for OCR A-level chemistry students.
ChemistryExplore the key mechanisms of electrophilic and nucleophilic reactions in benzene, including Friedel-Crafts acylation and alkylation. This summary covers essential organic reactions and their mechanisms, tailored for A-Level Chemistry students, particularly those following the OCR B Salters syllabus.
ChemistryExplore the key concepts of aromatic chemistry, including the structure and reactivity of benzene, electrophilic substitution mechanisms, and the role of delocalized electrons. This summary covers nitration and Friedel-Crafts reactions, comparing the reactivity of alkenes and arenes, and the unique properties of phenols. Ideal for A-Level organic chemistry students.
ChemistryExplore key mechanisms in aromatic chemistry, including electrophilic and nucleophilic substitution, Friedel-Crafts acylation, and reduction processes. This summary covers essential concepts for A-level organic chemistry, focusing on the synthesis routes of aromatic compounds and their transformations. Ideal for students preparing for exams or seeking to deepen their understanding of organic mechanisms.
ChemistryExplore the key electrophilic substitution reactions of benzene, including nitration, bromination, chlorination, alkylation, and acylation. This summary covers the mechanisms, catalysts, and products involved in each reaction, providing a clear understanding of benzene's reactivity in organic chemistry.
ChemistryExplore the mechanisms of nucleophilic substitution reactions in haloalkanes, including hydrolysis processes and bond enthalpy. This summary covers primary, secondary, and tertiary haloalkanes, common nucleophiles, and environmental impacts of organohalogen compounds. Ideal for A Level organic chemistry students.
ChemistryApp Store
Google Play
The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.
Stefan S
iOS user
This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.
Samantha Klich
Android user
Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.
Anna
iOS user
Best app on earth! no words because it’s too good
Thomas R
iOS user
Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.
Basil
Android user
This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.
David K
iOS user
The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!
Sudenaz Ocak
Android user
In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.
Greenlight Bonnie
Android user
very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.
Rohan U
Android user
I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didn’t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as I’m sure you too will see developments.
Xander S
iOS user
THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮
Elisha
iOS user
This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now
Paul T
iOS user
The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.
Stefan S
iOS user
This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.
Samantha Klich
Android user
Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.
Anna
iOS user
Best app on earth! no words because it’s too good
Thomas R
iOS user
Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.
Basil
Android user
This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.
David K
iOS user
The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!
Sudenaz Ocak
Android user
In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.
Greenlight Bonnie
Android user
very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.
Rohan U
Android user
I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didn’t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as I’m sure you too will see developments.
Xander S
iOS user
THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮
Elisha
iOS user
This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now
Paul T
iOS user
Poppy Sykes
@poppy_sykes
Halogenealkanes are organic compounds where hydrogen atoms in alkanes have been replaced by halogen atoms (fluorine, chlorine, bromine, or iodine). These compounds are incredibly useful in chemical synthesis because they can undergo two main types of reactions - nucleophilic substitution... Show more
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Ever wondered how chemists create the building blocks for everything from medicines to plastics? Halogenealkanes are your answer - they're like the Swiss Army knife of organic chemistry!
You can make halogenealkanes in several ways. The most common method is free radical substitution of alkanes, where UV light helps chlorine atoms replace hydrogen atoms. You can also use electrophilic addition - for example, adding HBr to ethene gives you bromoethane .
Another brilliant method involves treating alcohols with hydrogen halides. Want a chloroalkane? Treat your alcohol with PCl₅ or concentrated H₂SO₄ with KCl. For bromoalkanes, use 50% sulphuric acid with potassium bromide. Iodoalkanes are trickier since H₂SO₄ would oxidise the hydrogen iodide, so chemists use red phosphorus with iodine instead.
💡 Quick Tip: The rate of reaction with nucleophiles follows this pattern: iodo > bromo > chloro > fluoro. This happens because iodine forms the weakest C-halogen bond (largest atomic radius), whilst fluorine forms the strongest bond (smallest atomic radius).
Access to all documents
Improve your grades
Join milions of students
By signing up you accept Terms of Service and Privacy Policy
Here's where halogenealkanes really shine - they're incredibly versatile in reactions, and understanding these mechanisms will make organic chemistry so much clearer!
Nucleophilic substitution occurs when the halogen atom gets replaced by a nucleophile (something with a lone pair to donate). There are two main mechanisms: SN1 involves forming a carbocation intermediate (tertiary halogenealkanes love this route), whilst SN2 happens in one step with both the nucleophile attacking and the halogen leaving simultaneously (primary halogenealkanes prefer this).
You can create loads of useful compounds this way. Treat with aqueous NaOH under reflux to get alcohols, use potassium cyanide in ethanol to make nitriles (brilliant for extending carbon chains), or react with concentrated ammonia to form amines.
Elimination reactions are equally important - heat a halogenealkane with concentrated NaOH in ethanol, and you'll get an alkene plus water. Whether you get substitution or elimination depends on your conditions: aqueous solutions and lower temperatures favour substitution, whilst ethanolic solutions and higher temperatures push towards elimination.
💡 Remember: Primary halogenealkanes mainly undergo SN2 and substitution, tertiary ones prefer SN1 and elimination, whilst secondary ones can do both - it's all about stability!
Our AI Companion is a student-focused AI tool that offers more than just answers. Built on millions of Knowunity resources, it provides relevant information, personalised study plans, quizzes, and content directly in the chat, adapting to your individual learning journey.
You can download the app from Google Play Store and Apple App Store.
That's right! Enjoy free access to study content, connect with fellow students, and get instant help – all at your fingertips.
2
Smart Tools NEW
Transform this note into: ✓ 50+ Practice Questions ✓ Interactive Flashcards ✓ Full Mock Exam ✓ Essay Outlines
Explore key organic reaction mechanisms including electrophilic addition, electrophilic substitution, and nucleophilic substitution. This summary covers the reactions of alkenes, benzene, carbonyl compounds, and halogenoalkanes, detailing reactants, products, and conditions necessary for each mechanism. Ideal for OCR A-level chemistry students.
ChemistryExplore the key mechanisms of electrophilic and nucleophilic reactions in benzene, including Friedel-Crafts acylation and alkylation. This summary covers essential organic reactions and their mechanisms, tailored for A-Level Chemistry students, particularly those following the OCR B Salters syllabus.
ChemistryExplore the key concepts of aromatic chemistry, including the structure and reactivity of benzene, electrophilic substitution mechanisms, and the role of delocalized electrons. This summary covers nitration and Friedel-Crafts reactions, comparing the reactivity of alkenes and arenes, and the unique properties of phenols. Ideal for A-Level organic chemistry students.
ChemistryExplore key mechanisms in aromatic chemistry, including electrophilic and nucleophilic substitution, Friedel-Crafts acylation, and reduction processes. This summary covers essential concepts for A-level organic chemistry, focusing on the synthesis routes of aromatic compounds and their transformations. Ideal for students preparing for exams or seeking to deepen their understanding of organic mechanisms.
ChemistryExplore the key electrophilic substitution reactions of benzene, including nitration, bromination, chlorination, alkylation, and acylation. This summary covers the mechanisms, catalysts, and products involved in each reaction, providing a clear understanding of benzene's reactivity in organic chemistry.
ChemistryExplore the mechanisms of nucleophilic substitution reactions in haloalkanes, including hydrolysis processes and bond enthalpy. This summary covers primary, secondary, and tertiary haloalkanes, common nucleophiles, and environmental impacts of organohalogen compounds. Ideal for A Level organic chemistry students.
ChemistryApp Store
Google Play
The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.
Stefan S
iOS user
This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.
Samantha Klich
Android user
Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.
Anna
iOS user
Best app on earth! no words because it’s too good
Thomas R
iOS user
Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.
Basil
Android user
This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.
David K
iOS user
The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!
Sudenaz Ocak
Android user
In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.
Greenlight Bonnie
Android user
very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.
Rohan U
Android user
I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didn’t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as I’m sure you too will see developments.
Xander S
iOS user
THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮
Elisha
iOS user
This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now
Paul T
iOS user
The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.
Stefan S
iOS user
This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.
Samantha Klich
Android user
Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.
Anna
iOS user
Best app on earth! no words because it’s too good
Thomas R
iOS user
Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.
Basil
Android user
This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.
David K
iOS user
The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!
Sudenaz Ocak
Android user
In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.
Greenlight Bonnie
Android user
very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.
Rohan U
Android user
I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didn’t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as I’m sure you too will see developments.
Xander S
iOS user
THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮
Elisha
iOS user
This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now
Paul T
iOS user
Sociology