Ligands and Complex Formation
Ligands are electron donors that attach to transition metal ions to form coordination compounds or complexes. Think of them as molecules or ions with lone pairs of electrons that can form coordinate bonds with the metal.
Ligands are classified by how many bonds they can form - monodentate (one bond), bidentate (two bonds), up to hexadentate (six bonds). The coordination number tells you how many bonds the central metal ion has to ligands, which determines the shape of the complex.
Naming complexes follows specific rules that might seem complicated at first, but they're logical. You write ligands alphabetically, add prefixes for multiples (di, tri, tetra), and change endings for negative ion ligands to end in 'o'. Common ligands like water become 'aqua' and ammonia becomes 'ammine'.
Pro Tip: The formula goes in square brackets with the overall charge outside - this makes it clear what's part of the complex!