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4 Dec 2025

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Understanding Relative Atomic Mass: Calculations, Mass Spectrometry, and Isotopes

L

Lele c

@yousea123

Ever wondered how scientists work out the exact mass of... Show more

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Relative Mass and Charge
Specification:
be able to define the terms 'relative isotopic mass' and 'relative atomic mass',
based on the 12C sc

Understanding Relative Mass

You'll need to master several key definitions that all relate to comparing masses against carbon-12 as the standard. Think of carbon-12 as the "ruler" we use to measure everything else in chemistry.

Relative isotopic mass is simply the mass of one specific isotope compared to 1/12th of a carbon-12 atom. Meanwhile, relative atomic mass is more complex - it's the weighted average mass of all an element's isotopes, taking into account how common each one is.

To calculate relative atomic mass, use this formula: (Isotopicmass×percentageabundance)+(Isotopicmass×percentageabundance)(Isotopic mass × percentage abundance) + (Isotopic mass × percentage abundance)/100. You're basically finding the average, but giving more weight to the isotopes that appear more frequently.

Quick tip: Remember that relative atomic mass isn't just a simple average - it's weighted by how abundant each isotope is in nature!

Relative Mass and Charge
Specification:
be able to define the terms 'relative isotopic mass' and 'relative atomic mass',
based on the 12C sc

Calculating Molecular Masses

Working out relative molecular mass for diatomic molecules like chlorine requires probability calculations that might seem tricky at first, but follow a clear pattern.

For Cl₂, you calculate the chances of different combinations: two Cl-35 atoms, one of each isotope, or two Cl-37 atoms. If Cl-35 has a 3/4 chance, then two Cl-35 atoms have a (3/4 × 3/4) = 9/16 chance. Mixed pairs have twice the probability since they can occur in either order.

Mass spectrometry works through four stages: ionisation (electrons knock off outer electrons), acceleration (electric fields speed up the ions), deflection (electromagnets bend the path), and detection (measuring mass and charge). The whole process happens in a vacuum to prevent air interfering with results.

Remember: Lighter ions get deflected more than heavier ones - this separation is what lets us identify different masses!

Relative Mass and Charge
Specification:
be able to define the terms 'relative isotopic mass' and 'relative atomic mass',
based on the 12C sc

Quick Reference and Key Points

The vacuum in mass spectrometry is absolutely crucial - air would interfere with ion deflection and react with the ions themselves, completely messing up your results.

When interpreting mass spectra, the molecular ion peak (M⁺) gives you the relative molecular mass directly from its m/z value. For diatomic molecules, you'll see multiple peaks showing different isotope combinations.

Practice these calculations regularly because they're guaranteed exam material. The formulas might look intimidating, but they're just systematic ways of working out weighted averages and probabilities.

Exam success: Master the definitions word-perfect and practice calculating relative atomic mass from abundance data - these questions come up every year!



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Stefan S

iOS user

This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.

Samantha Klich

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Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.

Anna

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Best app on earth! no words because it’s too good

Thomas R

iOS user

Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.

Basil

Android user

This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.

David K

iOS user

The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!

Sudenaz Ocak

Android user

In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.

Greenlight Bonnie

Android user

very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.

Rohan U

Android user

I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didn’t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as I’m sure you too will see developments.

Xander S

iOS user

THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮

Elisha

iOS user

This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now

Paul T

iOS user

The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.

Stefan S

iOS user

This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.

Samantha Klich

Android user

Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.

Anna

iOS user

Best app on earth! no words because it’s too good

Thomas R

iOS user

Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.

Basil

Android user

This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.

David K

iOS user

The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!

Sudenaz Ocak

Android user

In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.

Greenlight Bonnie

Android user

very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.

Rohan U

Android user

I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didn’t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as I’m sure you too will see developments.

Xander S

iOS user

THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮

Elisha

iOS user

This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now

Paul T

iOS user

 

Chemistry

229

4 Dec 2025

3 pages

Understanding Relative Atomic Mass: Calculations, Mass Spectrometry, and Isotopes

L

Lele c

@yousea123

Ever wondered how scientists work out the exact mass of atoms and molecules? This is all about relative mass and how mass spectrometry helps us measure the tiniest particles with incredible precision.

Relative Mass and Charge
Specification:
be able to define the terms 'relative isotopic mass' and 'relative atomic mass',
based on the 12C sc

Sign up to see the contentIt's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Understanding Relative Mass

You'll need to master several key definitions that all relate to comparing masses against carbon-12 as the standard. Think of carbon-12 as the "ruler" we use to measure everything else in chemistry.

Relative isotopic mass is simply the mass of one specific isotope compared to 1/12th of a carbon-12 atom. Meanwhile, relative atomic mass is more complex - it's the weighted average mass of all an element's isotopes, taking into account how common each one is.

To calculate relative atomic mass, use this formula: (Isotopicmass×percentageabundance)+(Isotopicmass×percentageabundance)(Isotopic mass × percentage abundance) + (Isotopic mass × percentage abundance)/100. You're basically finding the average, but giving more weight to the isotopes that appear more frequently.

Quick tip: Remember that relative atomic mass isn't just a simple average - it's weighted by how abundant each isotope is in nature!

Relative Mass and Charge
Specification:
be able to define the terms 'relative isotopic mass' and 'relative atomic mass',
based on the 12C sc

Sign up to see the contentIt's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Calculating Molecular Masses

Working out relative molecular mass for diatomic molecules like chlorine requires probability calculations that might seem tricky at first, but follow a clear pattern.

For Cl₂, you calculate the chances of different combinations: two Cl-35 atoms, one of each isotope, or two Cl-37 atoms. If Cl-35 has a 3/4 chance, then two Cl-35 atoms have a (3/4 × 3/4) = 9/16 chance. Mixed pairs have twice the probability since they can occur in either order.

Mass spectrometry works through four stages: ionisation (electrons knock off outer electrons), acceleration (electric fields speed up the ions), deflection (electromagnets bend the path), and detection (measuring mass and charge). The whole process happens in a vacuum to prevent air interfering with results.

Remember: Lighter ions get deflected more than heavier ones - this separation is what lets us identify different masses!

Relative Mass and Charge
Specification:
be able to define the terms 'relative isotopic mass' and 'relative atomic mass',
based on the 12C sc

Sign up to see the contentIt's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Quick Reference and Key Points

The vacuum in mass spectrometry is absolutely crucial - air would interfere with ion deflection and react with the ions themselves, completely messing up your results.

When interpreting mass spectra, the molecular ion peak (M⁺) gives you the relative molecular mass directly from its m/z value. For diatomic molecules, you'll see multiple peaks showing different isotope combinations.

Practice these calculations regularly because they're guaranteed exam material. The formulas might look intimidating, but they're just systematic ways of working out weighted averages and probabilities.

Exam success: Master the definitions word-perfect and practice calculating relative atomic mass from abundance data - these questions come up every year!

We thought you’d never ask...

What is the Knowunity AI companion?

Our AI Companion is a student-focused AI tool that offers more than just answers. Built on millions of Knowunity resources, it provides relevant information, personalised study plans, quizzes, and content directly in the chat, adapting to your individual learning journey.

Where can I download the Knowunity app?

You can download the app from Google Play Store and Apple App Store.

Is Knowunity really free of charge?

That's right! Enjoy free access to study content, connect with fellow students, and get instant help – all at your fingertips.

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Most popular content in Chemistry

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Can't find what you're looking for? Explore other subjects.

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4.9/5

App Store

4.8/5

Google Play

The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.

Stefan S

iOS user

This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.

Samantha Klich

Android user

Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.

Anna

iOS user

Best app on earth! no words because it’s too good

Thomas R

iOS user

Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.

Basil

Android user

This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.

David K

iOS user

The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!

Sudenaz Ocak

Android user

In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.

Greenlight Bonnie

Android user

very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.

Rohan U

Android user

I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didn’t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as I’m sure you too will see developments.

Xander S

iOS user

THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮

Elisha

iOS user

This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now

Paul T

iOS user

The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.

Stefan S

iOS user

This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.

Samantha Klich

Android user

Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.

Anna

iOS user

Best app on earth! no words because it’s too good

Thomas R

iOS user

Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.

Basil

Android user

This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.

David K

iOS user

The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!

Sudenaz Ocak

Android user

In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.

Greenlight Bonnie

Android user

very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.

Rohan U

Android user

I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didn’t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as I’m sure you too will see developments.

Xander S

iOS user

THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮

Elisha

iOS user

This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now

Paul T

iOS user