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How Cool Chemical Reactions Happen: Electrophilic Addition, Hydration, and Friedel-Crafts!

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Zara

04/09/2025

Chemistry

AQA a level chemistry mechanisms

874

4 Sept 2025

4 pages

How Cool Chemical Reactions Happen: Electrophilic Addition, Hydration, and Friedel-Crafts!

user profile picture

Zara

@zara_ccce

A comprehensive guide to organic chemistry reactions focusing on addition,... Show more

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Transform this note into: ✓ 50+ Practice Questions ✓ Interactive Flashcards ✓ Full Mock Exam ✓ Essay Outlines

Mock Exam
Quiz
Flashcards
Essay
Electrophilic Addition
- with Bromine
- Sulfuric acid
H
H
Ege
CHOSOZOH
Hydrogen bromide
H
ruce
Gond
For
C₂OH
U
Elimination
-Ethanolic hydrox

Page 2: Multiple Reaction Mechanisms

This page covers several important reaction types including acid catalyzed addition hydration of ethene and free radical substitution mechanisms. The content emphasizes the step-wise nature of organic reactions.

Definition: Free radical substitution occurs through three distinct steps: initiation, propagation, and termination.

Example: The free radical bromination of methane proceeds through a chain reaction mechanism initiated by UV light.

Highlight: The propagation step demonstrates how radical chain reactions can be self-sustaining once initiated.

Vocabulary: Propagation - the main reaction cycle in a radical chain mechanism where reactive intermediates are continuously regenerated.

Electrophilic Addition
- with Bromine
- Sulfuric acid
H
H
Ege
CHOSOZOH
Hydrogen bromide
H
ruce
Gond
For
C₂OH
U
Elimination
-Ethanolic hydrox

Page 3: Nucleophilic Reactions

The third page explores nucleophilic addition and addition-elimination reactions, with particular focus on reactions involving ammonia and cyanide ions.

Definition: Nucleophilic addition involves the attack of an electron-rich species (nucleophile) on an electron-deficient carbon.

Example: The reaction of ammonia with carbonyls to form primary amines demonstrates nucleophilic addition followed by elimination.

Highlight: The formation of cyanohydrins shows how nucleophilic addition can create new carbon-carbon bonds.

Electrophilic Addition
- with Bromine
- Sulfuric acid
H
H
Ege
CHOSOZOH
Hydrogen bromide
H
ruce
Gond
For
C₂OH
U
Elimination
-Ethanolic hydrox

Page 4: Aromatic Substitution Reactions

The final page details aromatic substitution reactions, including nitration and the Friedel-Crafts acylation mechanism.

Definition: Electrophilic aromatic substitution involves the replacement of a hydrogen atom on an aromatic ring with an electrophile.

Example: The nitration of aromatic compounds using nitric acid and sulfuric acid demonstrates the formation and reaction of the nitronium ion (NO₂⁺).

Highlight: The Friedel-Crafts acylation requires aluminum chloride as a Lewis acid catalyst to generate the active electrophile.

Vocabulary: Electrophile - a chemical species that accepts electron pairs in chemical bonds.

Electrophilic Addition
- with Bromine
- Sulfuric acid
H
H
Ege
CHOSOZOH
Hydrogen bromide
H
ruce
Gond
For
C₂OH
U
Elimination
-Ethanolic hydrox

Page 1: Electrophilic Addition Reactions

The first page introduces fundamental electrophilic addition reactions, particularly focusing on reactions with bromine and sulfuric acid. The mechanisms show the step-by-step addition of reactants across double bonds.

Definition: Electrophilic addition is a reaction where an electrophile (electron-seeking species) adds across a carbon-carbon double bond.

Example: The addition of bromine (Br₂) to an alkene produces a dibrominated product through a cyclic bromonium ion intermediate.

Highlight: The reaction mechanism demonstrates the importance of electron movement and intermediate formation in organic chemistry reactions.

Vocabulary: Bromonium ion - a cyclic intermediate formed during bromine addition to alkenes.



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4.9/5

App Store

4.8/5

Google Play

The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.

Stefan S

iOS user

This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.

Samantha Klich

Android user

Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.

Anna

iOS user

Best app on earth! no words because it’s too good

Thomas R

iOS user

Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.

Basil

Android user

This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.

David K

iOS user

The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!

Sudenaz Ocak

Android user

In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.

Greenlight Bonnie

Android user

very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.

Rohan U

Android user

I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didn’t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as I’m sure you too will see developments.

Xander S

iOS user

THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮

Elisha

iOS user

This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now

Paul T

iOS user

The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.

Stefan S

iOS user

This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.

Samantha Klich

Android user

Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.

Anna

iOS user

Best app on earth! no words because it’s too good

Thomas R

iOS user

Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.

Basil

Android user

This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.

David K

iOS user

The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!

Sudenaz Ocak

Android user

In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.

Greenlight Bonnie

Android user

very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.

Rohan U

Android user

I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didn’t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as I’m sure you too will see developments.

Xander S

iOS user

THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮

Elisha

iOS user

This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now

Paul T

iOS user

 

Chemistry

874

4 Sept 2025

4 pages

How Cool Chemical Reactions Happen: Electrophilic Addition, Hydration, and Friedel-Crafts!

user profile picture

Zara

@zara_ccce

A comprehensive guide to organic chemistry reactions focusing on addition, substitution, and elimination mechanisms, with detailed explanations of electrophilic addition with bromine, acid catalyzed addition hydration of ethene, and Friedel-Crafts acylation mechanism.

  • Covers major reaction types including... Show more

Electrophilic Addition
- with Bromine
- Sulfuric acid
H
H
Ege
CHOSOZOH
Hydrogen bromide
H
ruce
Gond
For
C₂OH
U
Elimination
-Ethanolic hydrox

Sign up to see the contentIt's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Page 2: Multiple Reaction Mechanisms

This page covers several important reaction types including acid catalyzed addition hydration of ethene and free radical substitution mechanisms. The content emphasizes the step-wise nature of organic reactions.

Definition: Free radical substitution occurs through three distinct steps: initiation, propagation, and termination.

Example: The free radical bromination of methane proceeds through a chain reaction mechanism initiated by UV light.

Highlight: The propagation step demonstrates how radical chain reactions can be self-sustaining once initiated.

Vocabulary: Propagation - the main reaction cycle in a radical chain mechanism where reactive intermediates are continuously regenerated.

Electrophilic Addition
- with Bromine
- Sulfuric acid
H
H
Ege
CHOSOZOH
Hydrogen bromide
H
ruce
Gond
For
C₂OH
U
Elimination
-Ethanolic hydrox

Sign up to see the contentIt's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Page 3: Nucleophilic Reactions

The third page explores nucleophilic addition and addition-elimination reactions, with particular focus on reactions involving ammonia and cyanide ions.

Definition: Nucleophilic addition involves the attack of an electron-rich species (nucleophile) on an electron-deficient carbon.

Example: The reaction of ammonia with carbonyls to form primary amines demonstrates nucleophilic addition followed by elimination.

Highlight: The formation of cyanohydrins shows how nucleophilic addition can create new carbon-carbon bonds.

Electrophilic Addition
- with Bromine
- Sulfuric acid
H
H
Ege
CHOSOZOH
Hydrogen bromide
H
ruce
Gond
For
C₂OH
U
Elimination
-Ethanolic hydrox

Sign up to see the contentIt's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Page 4: Aromatic Substitution Reactions

The final page details aromatic substitution reactions, including nitration and the Friedel-Crafts acylation mechanism.

Definition: Electrophilic aromatic substitution involves the replacement of a hydrogen atom on an aromatic ring with an electrophile.

Example: The nitration of aromatic compounds using nitric acid and sulfuric acid demonstrates the formation and reaction of the nitronium ion (NO₂⁺).

Highlight: The Friedel-Crafts acylation requires aluminum chloride as a Lewis acid catalyst to generate the active electrophile.

Vocabulary: Electrophile - a chemical species that accepts electron pairs in chemical bonds.

Electrophilic Addition
- with Bromine
- Sulfuric acid
H
H
Ege
CHOSOZOH
Hydrogen bromide
H
ruce
Gond
For
C₂OH
U
Elimination
-Ethanolic hydrox

Sign up to see the contentIt's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Page 1: Electrophilic Addition Reactions

The first page introduces fundamental electrophilic addition reactions, particularly focusing on reactions with bromine and sulfuric acid. The mechanisms show the step-by-step addition of reactants across double bonds.

Definition: Electrophilic addition is a reaction where an electrophile (electron-seeking species) adds across a carbon-carbon double bond.

Example: The addition of bromine (Br₂) to an alkene produces a dibrominated product through a cyclic bromonium ion intermediate.

Highlight: The reaction mechanism demonstrates the importance of electron movement and intermediate formation in organic chemistry reactions.

Vocabulary: Bromonium ion - a cyclic intermediate formed during bromine addition to alkenes.

We thought you’d never ask...

What is the Knowunity AI companion?

Our AI Companion is a student-focused AI tool that offers more than just answers. Built on millions of Knowunity resources, it provides relevant information, personalised study plans, quizzes, and content directly in the chat, adapting to your individual learning journey.

Where can I download the Knowunity app?

You can download the app from Google Play Store and Apple App Store.

Is Knowunity really free of charge?

That's right! Enjoy free access to study content, connect with fellow students, and get instant help – all at your fingertips.

Smart Tools NEW

Transform this note into: ✓ 50+ Practice Questions ✓ Interactive Flashcards ✓ Full Mock Exam ✓ Essay Outlines

Mock Exam
Quiz
Flashcards
Essay

Can't find what you're looking for? Explore other subjects.

Students love us — and so will you.

4.9/5

App Store

4.8/5

Google Play

The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.

Stefan S

iOS user

This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.

Samantha Klich

Android user

Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.

Anna

iOS user

Best app on earth! no words because it’s too good

Thomas R

iOS user

Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.

Basil

Android user

This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.

David K

iOS user

The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!

Sudenaz Ocak

Android user

In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.

Greenlight Bonnie

Android user

very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.

Rohan U

Android user

I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didn’t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as I’m sure you too will see developments.

Xander S

iOS user

THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮

Elisha

iOS user

This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now

Paul T

iOS user

The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.

Stefan S

iOS user

This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.

Samantha Klich

Android user

Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.

Anna

iOS user

Best app on earth! no words because it’s too good

Thomas R

iOS user

Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.

Basil

Android user

This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.

David K

iOS user

The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!

Sudenaz Ocak

Android user

In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.

Greenlight Bonnie

Android user

very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.

Rohan U

Android user

I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didn’t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as I’m sure you too will see developments.

Xander S

iOS user

THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮

Elisha

iOS user

This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now

Paul T

iOS user