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How Zinc Carbonate Breaks Down with Gibbs Free Energy!

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Aasiyah Rahman

05/04/2023

Chemistry

Phyisical Chemistry- Thermodynamics, Gibbs free energy

How Zinc Carbonate Breaks Down with Gibbs Free Energy!

A comprehensive guide to Gibbs free energy feasibility calculation and thermodynamics enthalpy entropy reaction concepts, focusing on determining reaction feasibility through temperature variations.

  • Gibbs free energy (ΔG) serves as the key indicator for reaction feasibility, calculated using enthalpy (ΔH) and entropy (ΔS)
  • Reactions are considered feasible when ΔG is negative, while positive values indicate non-feasibility
  • Temperature plays a crucial role in determining reaction feasibility, with reactions often being feasible only within specific temperature ranges
  • The zinc carbonate decomposition temperature range demonstrates practical application of these principles
  • Understanding spontaneity versus feasibility helps distinguish between theoretical possibility and practical occurrence
...

05/04/2023

86

Thermodynamics
6 Gibbs Free Energy
KJ MOI" KJ mol" k
K
AGAH-TAS
Change in
Gilolos free charge
energy
find as;
enthalpy temp entropy
Chorge
f

View

Page 2: Temperature Effects on Reaction Feasibility

This page explores how temperature affects reaction feasibility through various combinations of enthalpy and entropy values, using the decomposition of zinc carbonate as a practical example.

Example: The decomposition of zinc carbonate ZnCO3ZnCO₃ to zinc oxide ZnOZnO and carbon dioxide CO2CO₂ demonstrates how temperature influences reaction feasibility.

Highlight: Different combinations of positive and negative ΔH and ΔS values lead to distinct temperature-dependent feasibility patterns.

The page presents a comprehensive table showing how ΔG varies with temperature under different conditions, providing a clear framework for predicting reaction feasibility at various temperatures.

Thermodynamics
6 Gibbs Free Energy
KJ MOI" KJ mol" k
K
AGAH-TAS
Change in
Gilolos free charge
energy
find as;
enthalpy temp entropy
Chorge
f

View

Page 3: Practical Calculations and Applications

This page focuses on practical calculations involving Gibbs free energy and determining specific temperature ranges for reaction feasibility.

Definition: The transition temperature whenΔG=0when ΔG = 0 marks the point where a reaction switches between feasible and non-feasible states.

Example: Calculations show that the zinc carbonate decomposition becomes feasible above 411K, demonstrating the practical application of these principles.

Highlight: The melting point of substances represents a specific case where ΔG = 0, marking the transition to feasibility for the melting process.

The page provides detailed mathematical procedures for calculating transition temperatures and analyzing feasibility at specific temperatures.

Thermodynamics
6 Gibbs Free Energy
KJ MOI" KJ mol" k
K
AGAH-TAS
Change in
Gilolos free charge
energy
find as;
enthalpy temp entropy
Chorge
f

View

Page 4: [No content provided for page 4]

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Chemistry

86

5 Apr 2023

4 pages

How Zinc Carbonate Breaks Down with Gibbs Free Energy!

user profile picture

Aasiyah Rahman

@aasiyahrahman

A comprehensive guide to Gibbs free energy feasibility calculation and thermodynamics enthalpy entropy reaction concepts, focusing on determining reaction feasibility through temperature variations.

  • Gibbs free energy (ΔG) serves as the key indicator for reaction feasibility, calculated using enthalpy (ΔH) and... Show more

Thermodynamics
6 Gibbs Free Energy
KJ MOI" KJ mol" k
K
AGAH-TAS
Change in
Gilolos free charge
energy
find as;
enthalpy temp entropy
Chorge
f

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Page 2: Temperature Effects on Reaction Feasibility

This page explores how temperature affects reaction feasibility through various combinations of enthalpy and entropy values, using the decomposition of zinc carbonate as a practical example.

Example: The decomposition of zinc carbonate ZnCO3ZnCO₃ to zinc oxide ZnOZnO and carbon dioxide CO2CO₂ demonstrates how temperature influences reaction feasibility.

Highlight: Different combinations of positive and negative ΔH and ΔS values lead to distinct temperature-dependent feasibility patterns.

The page presents a comprehensive table showing how ΔG varies with temperature under different conditions, providing a clear framework for predicting reaction feasibility at various temperatures.

Thermodynamics
6 Gibbs Free Energy
KJ MOI" KJ mol" k
K
AGAH-TAS
Change in
Gilolos free charge
energy
find as;
enthalpy temp entropy
Chorge
f

Sign up to see the contentIt's free!

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By signing up you accept Terms of Service and Privacy Policy

Page 3: Practical Calculations and Applications

This page focuses on practical calculations involving Gibbs free energy and determining specific temperature ranges for reaction feasibility.

Definition: The transition temperature whenΔG=0when ΔG = 0 marks the point where a reaction switches between feasible and non-feasible states.

Example: Calculations show that the zinc carbonate decomposition becomes feasible above 411K, demonstrating the practical application of these principles.

Highlight: The melting point of substances represents a specific case where ΔG = 0, marking the transition to feasibility for the melting process.

The page provides detailed mathematical procedures for calculating transition temperatures and analyzing feasibility at specific temperatures.

Thermodynamics
6 Gibbs Free Energy
KJ MOI" KJ mol" k
K
AGAH-TAS
Change in
Gilolos free charge
energy
find as;
enthalpy temp entropy
Chorge
f

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Page 4: [No content provided for page 4]

Thermodynamics
6 Gibbs Free Energy
KJ MOI" KJ mol" k
K
AGAH-TAS
Change in
Gilolos free charge
energy
find as;
enthalpy temp entropy
Chorge
f

Sign up to see the contentIt's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Page 1: Understanding Gibbs Free Energy

This page introduces the fundamental concepts of Gibbs free energy and its relationship to reaction feasibility. The equation ΔG = ΔH - TΔS forms the cornerstone of determining whether reactions can occur spontaneously.

Definition: Gibbs free energy ΔGΔG is a thermodynamic quantity that determines reaction feasibility, combining both enthalpy and entropy effects.

Highlight: A negative ΔG indicates a feasible reaction, while a positive ΔG indicates a non-feasible reaction.

Vocabulary: Spontaneous reactions are those that are thermodynamically feasible but may still require activation energy to proceed.

The page emphasizes the importance of unit conversions, particularly from kJ to J multiplyingby1000multiplying by 1000 and the significance of temperature in determining reaction feasibility.

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