Crude Oil to Useful Products
Crude oil gets transformed into valuable chemicals through fractional distillation and catalytic cracking. The cracking process uses zeolite catalysts at around 500°C with slight pressure to break long hydrocarbon chains into more useful shorter ones.
There are two main cracking methods: thermal cracking (1000°C, 70 atm) and catalytic cracking (cheaper, milder conditions). Both produce alkanes and alkenes that serve as building blocks for everything from fuels to plastics.
Complete combustion of hydrocarbons with excess oxygen produces just CO₂ and H₂O. However, incomplete combustion creates nasty pollutants like carbon monoxide (toxic), sulfur compounds (acid rain), and unburnt hydrocarbons (smog).
Key Tip: Remember that catalytic cracking is cheaper and more efficient than thermal cracking - this often comes up in exam questions!
Alkenes and Addition Reactions
Alkenes are reactive because of their C=C double bond, making them perfect for electrophilic addition reactions. When hydrogen halides add to alkenes, they follow specific patterns based on carbocation stability: tertiary (3°) > secondary (2°) > primary (1°).
Addition polymerisation joins many alkene molecules together to form polymers. These long-chain molecules are incredibly useful but create environmental problems because they're non-biodegradable - their non-polar, stable structure resists breakdown.
The hydration of alkenes involves adding water across the double bond, often using concentrated H₂SO₄. This process can be reversed through dehydration using concentrated acids under reflux conditions.