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Mastering Electrolysis Half Equations for HT GCSE

Electrolysis might sound complex, but it's essentially about moving electrons... Show more

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127
Chemistry
Electrolysis Half equations - HT
-lons-
Li+ Gains an election →
Mg 2+ Gains two elections → Meg.
a Lose one electrons C
02- Lo

Understanding Electron Movement in Ions

Ever wondered how atoms become charged? It's all about electron transfer, and once you get the pattern, it becomes straightforward.

When metals like lithium (Li⁺) or magnesium (Mg²⁺) have positive charges, they need to gain electrons to become neutral atoms again. The number tells you exactly how many electrons they need - Li⁺ gains one electron, whilst Mg²⁺ gains two electrons.

Non-metals work the opposite way. Chloride ions (Cl⁻) and oxide ions (O²⁻) have negative charges because they have extra electrons. To become neutral atoms, they must lose electrons - chloride loses one, oxide loses two.

Quick Tip: The number in the charge always tells you exactly how many electrons are gained or lost!

During electrolysis, positive ions head to the negative electrode (cathode) where they pick up the electrons they need. It's like opposite charges attracting - the aluminium ions (Al³⁺) grab three electrons to become aluminium metal.

127
Chemistry
Electrolysis Half equations - HT
-lons-
Li+ Gains an election →
Mg 2+ Gains two elections → Meg.
a Lose one electrons C
02- Lo

Mastering Half Equations

Writing half equations becomes easy when you remember two key rules: balance the atoms and balance the charge.

Don't forget that many non-metals exist as diatomic molecules - Cl₂, Br₂, I₂, O₂, and H₂. This means you'll often need to double up your ions to make the equation work properly.

At the cathode (negative electrode), positive ions gain electrons. For example: Mg²⁺ + 2e⁻ → Mg. The electrons always appear on the left side because they're being added to the ion.

Remember: Cathode = positive ions gaining electrons, Anode = negative ions losing electrons!

At the anode (positive electrode), negative ions lose electrons. For chloride: 2Cl⁻ → Cl₂ + 2e⁻. Notice how we need two chloride ions to make one chlorine molecule, and the electrons appear on the right because they're being removed.

127
Chemistry
Electrolysis Half equations - HT
-lons-
Li+ Gains an election →
Mg 2+ Gains two elections → Meg.
a Lose one electrons C
02- Lo

OIL RIG - Your Memory Trick

OIL RIG is your best friend for remembering electron movement: Oxidation Is Loss, Reduction Is Gain (of electrons).

Every half equation shows either oxidation or reduction happening. At the cathode, ions like Ca²⁺ + 2e⁻ → Ca show reduction because electrons are gained. At the anode, reactions like 2Br⁻ → Br₂ + 2e⁻ show oxidation because electrons are lost.

Balancing becomes straightforward once you know the pattern. Count the charges on both sides - they must be equal. If Ca²⁺ needs to become Ca, it needs exactly 2 electrons to balance the 2+ charge.

Pro Tip: Always check your balanced equation - the total charge on the left must equal the total charge on the right!

The challenge questions test whether you truly understand the process. For potassium oxide electrolysis, K⁺ ions go to the cathode (gaining 1 electron each), whilst O²⁻ ions head to the anode (losing electrons to form oxygen gas).

127
Chemistry
Electrolysis Half equations - HT
-lons-
Li+ Gains an election →
Mg 2+ Gains two elections → Meg.
a Lose one electrons C
02- Lo

Applying Your Knowledge

Now you can tackle any electrolysis problem by breaking it down into simple steps.

For calcium oxide electrolysis, start by identifying what happens where. Calcium ions (Ca²⁺) are positive, so they're attracted to the negative cathode. There, each ion gains exactly two electrons to become a neutral calcium atom.

Writing the half equations becomes systematic. At the cathode: Ca²⁺ + 2e⁻ → Ca. At the anode, oxide ions lose electrons: 2O²⁻ → O₂ + 4e⁻. Notice how we need two oxide ions to make one oxygen molecule.

Success Strategy: Always identify the charges first, then work out how many electrons are needed to balance!

Finally, identify oxidation and reduction using OIL RIG. The oxide ions lose electrons (oxidation), whilst the calcium ions gain electrons (reduction). Every electrolysis involves both processes happening simultaneously at different electrodes.



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I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didn’t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as I’m sure you too will see developments.

Xander S

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THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮

Elisha

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This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now

Paul T

iOS user

The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.

Stefan S

iOS user

This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.

Samantha Klich

Android user

Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.

Anna

iOS user

Best app on earth! no words because it’s too good

Thomas R

iOS user

Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.

Basil

Android user

This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.

David K

iOS user

The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!

Sudenaz Ocak

Android user

In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.

Greenlight Bonnie

Android user

very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.

Rohan U

Android user

I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didn’t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as I’m sure you too will see developments.

Xander S

iOS user

THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮

Elisha

iOS user

This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now

Paul T

iOS user

 

Chemistry

294

16 Dec 2025

4 pages

Mastering Electrolysis Half Equations for HT GCSE

Electrolysis might sound complex, but it's essentially about moving electrons around to break down compounds. You'll master half equations by understanding which particles gain or lose electrons and how to balance these reactions properly.

127
Chemistry
Electrolysis Half equations - HT
-lons-
Li+ Gains an election →
Mg 2+ Gains two elections → Meg.
a Lose one electrons C
02- Lo

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Understanding Electron Movement in Ions

Ever wondered how atoms become charged? It's all about electron transfer, and once you get the pattern, it becomes straightforward.

When metals like lithium (Li⁺) or magnesium (Mg²⁺) have positive charges, they need to gain electrons to become neutral atoms again. The number tells you exactly how many electrons they need - Li⁺ gains one electron, whilst Mg²⁺ gains two electrons.

Non-metals work the opposite way. Chloride ions (Cl⁻) and oxide ions (O²⁻) have negative charges because they have extra electrons. To become neutral atoms, they must lose electrons - chloride loses one, oxide loses two.

Quick Tip: The number in the charge always tells you exactly how many electrons are gained or lost!

During electrolysis, positive ions head to the negative electrode (cathode) where they pick up the electrons they need. It's like opposite charges attracting - the aluminium ions (Al³⁺) grab three electrons to become aluminium metal.

127
Chemistry
Electrolysis Half equations - HT
-lons-
Li+ Gains an election →
Mg 2+ Gains two elections → Meg.
a Lose one electrons C
02- Lo

Sign up to see the contentIt's free!

Access to all documents

Improve your grades

Join milions of students

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Mastering Half Equations

Writing half equations becomes easy when you remember two key rules: balance the atoms and balance the charge.

Don't forget that many non-metals exist as diatomic molecules - Cl₂, Br₂, I₂, O₂, and H₂. This means you'll often need to double up your ions to make the equation work properly.

At the cathode (negative electrode), positive ions gain electrons. For example: Mg²⁺ + 2e⁻ → Mg. The electrons always appear on the left side because they're being added to the ion.

Remember: Cathode = positive ions gaining electrons, Anode = negative ions losing electrons!

At the anode (positive electrode), negative ions lose electrons. For chloride: 2Cl⁻ → Cl₂ + 2e⁻. Notice how we need two chloride ions to make one chlorine molecule, and the electrons appear on the right because they're being removed.

127
Chemistry
Electrolysis Half equations - HT
-lons-
Li+ Gains an election →
Mg 2+ Gains two elections → Meg.
a Lose one electrons C
02- Lo

Sign up to see the contentIt's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

OIL RIG - Your Memory Trick

OIL RIG is your best friend for remembering electron movement: Oxidation Is Loss, Reduction Is Gain (of electrons).

Every half equation shows either oxidation or reduction happening. At the cathode, ions like Ca²⁺ + 2e⁻ → Ca show reduction because electrons are gained. At the anode, reactions like 2Br⁻ → Br₂ + 2e⁻ show oxidation because electrons are lost.

Balancing becomes straightforward once you know the pattern. Count the charges on both sides - they must be equal. If Ca²⁺ needs to become Ca, it needs exactly 2 electrons to balance the 2+ charge.

Pro Tip: Always check your balanced equation - the total charge on the left must equal the total charge on the right!

The challenge questions test whether you truly understand the process. For potassium oxide electrolysis, K⁺ ions go to the cathode (gaining 1 electron each), whilst O²⁻ ions head to the anode (losing electrons to form oxygen gas).

127
Chemistry
Electrolysis Half equations - HT
-lons-
Li+ Gains an election →
Mg 2+ Gains two elections → Meg.
a Lose one electrons C
02- Lo

Sign up to see the contentIt's free!

Access to all documents

Improve your grades

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By signing up you accept Terms of Service and Privacy Policy

Applying Your Knowledge

Now you can tackle any electrolysis problem by breaking it down into simple steps.

For calcium oxide electrolysis, start by identifying what happens where. Calcium ions (Ca²⁺) are positive, so they're attracted to the negative cathode. There, each ion gains exactly two electrons to become a neutral calcium atom.

Writing the half equations becomes systematic. At the cathode: Ca²⁺ + 2e⁻ → Ca. At the anode, oxide ions lose electrons: 2O²⁻ → O₂ + 4e⁻. Notice how we need two oxide ions to make one oxygen molecule.

Success Strategy: Always identify the charges first, then work out how many electrons are needed to balance!

Finally, identify oxidation and reduction using OIL RIG. The oxide ions lose electrons (oxidation), whilst the calcium ions gain electrons (reduction). Every electrolysis involves both processes happening simultaneously at different electrodes.

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What is the Knowunity AI companion?

Our AI Companion is a student-focused AI tool that offers more than just answers. Built on millions of Knowunity resources, it provides relevant information, personalised study plans, quizzes, and content directly in the chat, adapting to your individual learning journey.

Where can I download the Knowunity app?

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Is Knowunity really free of charge?

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Can't find what you're looking for? Explore other subjects.

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4.8/5

Google Play

The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.

Stefan S

iOS user

This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.

Samantha Klich

Android user

Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.

Anna

iOS user

Best app on earth! no words because it’s too good

Thomas R

iOS user

Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.

Basil

Android user

This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.

David K

iOS user

The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!

Sudenaz Ocak

Android user

In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.

Greenlight Bonnie

Android user

very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.

Rohan U

Android user

I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didn’t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as I’m sure you too will see developments.

Xander S

iOS user

THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮

Elisha

iOS user

This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now

Paul T

iOS user

The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.

Stefan S

iOS user

This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.

Samantha Klich

Android user

Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.

Anna

iOS user

Best app on earth! no words because it’s too good

Thomas R

iOS user

Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.

Basil

Android user

This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.

David K

iOS user

The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!

Sudenaz Ocak

Android user

In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.

Greenlight Bonnie

Android user

very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.

Rohan U

Android user

I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didn’t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as I’m sure you too will see developments.

Xander S

iOS user

THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮

Elisha

iOS user

This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now

Paul T

iOS user