Covalent Bonding Basics
Think of covalent bonds as atoms playing a sharing game with electrons. When non-metal atoms react together, they don't give or take electrons like in ionic bonding - instead, they share them to fill their outer shells. Each shared pair creates one strong covalent bond.
These bonds pack a real punch because there's a powerful electrostatic attraction between the positive nucleus and the negative shared electrons. You'll often see this drawn in dot and cross diagrams, where different symbols show which electrons came from which atom.
Most covalent compounds have a simple molecular structure like CO₂ or H₂O. Whilst the atoms within each molecule are held together by incredibly strong covalent bonds, the forces between separate molecules are surprisingly weak.
This weakness between molecules explains why many covalent substances are gases or liquids at room temperature - it doesn't take much energy to separate the molecules from each other. They also don't conduct electricity because there aren't any free-moving electrons or ions floating about.
Quick Tip: Remember that covalent bonds are strong WITHIN molecules, but weak BETWEEN molecules - this is key to understanding their properties!
Diamond - Nature's Hardest Material
Diamond proves that carbon can be absolutely stunning in more ways than one. Each carbon atom forms four covalent bonds in a rigid, three-dimensional network that makes diamond incredibly hard - perfect for cutting tools and drill bits.
The high melting point of diamond comes from those strong covalent bonds that need enormous amounts of energy to break. However, don't expect diamond to power your phone - it doesn't conduct electricity because all electrons are locked up in covalent bonds.
Pure diamond appears colourless and transparent, though impurities can create those fancy coloured diamonds you see in jewellery shops.
Graphite - The Slippery Cousin
Graphite couldn't be more different from diamond, even though they're both pure carbon. Here, each carbon atom only forms three covalent bonds, creating flat sheets of carbon atoms arranged in hexagonal rings.
These sheets can slide over each other easily because they're held together by weak forces - that's why graphite feels slippery and works brilliantly as pencil 'lead'. Despite this sliding ability, graphite still has a high melting point because you'd need to break those strong covalent bonds within the sheets.
Unlike diamond, graphite conducts electricity thanks to delocalised electrons that can move freely between the layers. A single layer of graphite is called graphene - an amazing material that's strong, thin, transparent, and incredibly lightweight.
Fullerenes - Football-Shaped Molecules
Fullerenes are like carbon's creative phase - instead of forming giant structures like diamond or graphite, they create hollow balls and tubes that look remarkably like footballs or tiny straws.
These aren't giant covalent structures but rather large molecules containing different numbers of carbon atoms arranged in rings. The most famous fullerene contains 60 carbon atoms and is nicknamed 'buckyballs' after the architect Buckminster Fuller.
Like graphite, fullerenes have delocalised electrons that allow them to conduct electricity. Their boiling points are high compared to simple molecules, but not quite as extreme as diamond or graphite since they're still individual molecules rather than giant networks.
Real-World Connection: Fullerenes are being researched for everything from drug delivery systems to superconductors - showing how understanding bonding can lead to cutting-edge technology!