Atomic Structure and Numbers
Every atom is basically like a tiny solar system with a central nucleus surrounded by electrons spinning around in areas called shells. It's actually quite straightforward once you get the hang of it!
The atomic number tells you how many protons are packed into the nucleus - and here's the clever bit: all atoms of the same element always have identical atomic numbers. So every carbon atom has 6 protons, every oxygen atom has 8 protons, and so on.
In any neutral atom, you've got equal numbers of protons and electrons. This means the number of electrons always equals the atomic number too. The mass number is simply the total of protons plus neutrons, so if you want to find neutrons, just subtract the atomic number from the mass number.
Quick Tip: For chlorine-35, the mass number is 35 and atomic number is 17, so it has 17 protons, 17 electrons, and 18 neutrons (35-17=18).
Subatomic Particles and Historical Development
Subatomic particles each have their own personality: protons carry a +1 charge and have mass 1, neutrons are neutral with mass 1, and electrons have a -1 charge but are incredibly light mass1/1835.
Back in 1803, Dalton thought atoms were indestructible building blocks that couldn't be broken down. He reckoned atoms of the same element were identical and just got rearranged during chemical reactions - pretty smart for his time!
However, Dalton's ideas needed updating once scientists discovered that atoms actually contain smaller particles. We now know atoms can be split into protons, neutrons, and electrons, proving they're not the indivisible units Dalton imagined.
Isotopes are atoms of the same element with identical numbers of protons and electrons but different numbers of neutrons. They have the same atomic number but different mass numbers - think of them as atomic siblings with different weights!
Remember: Isotopes behave almost identically in chemical reactions because they have the same electron arrangement, but their different masses make them useful in various applications.