Maths
Chemistry
Biology
English Language
History
Responding to change (a2 only)
Infection and response
Homeostasis and response
Energy transfers (a2 only)
Cell biology
Organisms respond to changes in their internal and external environments (a-level only)
Biological molecules
Organisation
Substance exchange
Bioenergetics
Genetic information & variation
Inheritance, variation and evolution
Genetics & ecosystems (a2 only)
Ecology
Cells
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Britain & the wider world: 1745 -1901
1l the quest for political stability: germany, 1871-1991
The cold war
Inter-war germany
Medieval period: 1066 -1509
2d religious conflict and the church in england, c1529-c1570
2o democracy and nazism: germany, 1918-1945
1f industrialisation and the people: britain, c1783-1885
1c the tudors: england, 1485-1603
2m wars and welfare: britain in transition, 1906-1957
World war two & the holocaust
2n revolution and dictatorship: russia, 1917-1953
2s the making of modern britain, 1951-2007
World war one
Britain: 1509 -1745
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258
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29 Nov 2025
•
jessica
@jessicaa7
Aromatic chemistry centres around benzene, a remarkably stable ring-shaped molecule... Show more
Ever wondered why benzene (C₆H₆) is so special compared to other hydrocarbons? This cyclic, planar molecule has each carbon bonded to two other carbons and one hydrogen, with the remaining electron sitting in a p-orbital above and below the ring.
What makes benzene truly unique is its delocalised electron structure. Unlike what you'd expect from alternating single and double bonds, all C-C bonds are exactly the same length (139pm). This delocalisation creates extraordinary stability.
Scientists prove benzene's stability by comparing enthalpy of hydrogenation values. If benzene had three separate double bonds like cyclohexatriene, we'd expect -360 kJ/mol, but it's actually much less negative, showing benzene needs more energy to break its bonds.
Key Insight: Benzene's stability comes from delocalised electrons forming a 'ring of charge' above and below the carbon atoms.
Arenes (aromatic compounds) can be named in two ways: either as substituted benzenes (like bromobenzene) or with benzene as a phenyl functional group (like phenylamine for C₆H₅NH₂). The naming depends on which part of the molecule is more significant.
Benzene's stability creates a problem - it's too stable to react easily! However, chemists have developed clever ways to make it react through electrophilic substitution rather than addition reactions that would destroy the stable ring.
Friedel-Crafts acylation uses a halogen carrier catalyst like AlCl₃ to create a powerful electrophile. The catalyst polarises an acyl chloride (RCOCl), forming a carbocation that's strong enough to attack benzene's electron-rich ring. Under reflux with dry ether, this produces phenylketones.
The reaction mechanism involves the delocalised electrons attacking the electrophile, temporarily breaking the ring's stability. A hydrogen is then removed, reforming the aromatic ring with the new acyl group attached.
Exam Tip: Remember that benzene undergoes substitution, not addition - this preserves the stable aromatic ring structure.
Nitration of benzene creates nitrobenzene, essential for making explosives and dyes. Concentrated nitric and sulfuric acids react to form the nitronium ion (NO₂⁺), a powerful electrophile. Keep temperatures below 55°C to avoid multiple substitutions - too hot and you'll get unwanted products!
Our AI Companion is a student-focused AI tool that offers more than just answers. Built on millions of Knowunity resources, it provides relevant information, personalised study plans, quizzes, and content directly in the chat, adapting to your individual learning journey.
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The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.
Stefan S
iOS user
This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.
Samantha Klich
Android user
Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.
Anna
iOS user
Best app on earth! no words because it’s too good
Thomas R
iOS user
Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.
Basil
Android user
This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.
David K
iOS user
The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!
Sudenaz Ocak
Android user
In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.
Greenlight Bonnie
Android user
very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.
Rohan U
Android user
I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didn’t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as I’m sure you too will see developments.
Xander S
iOS user
THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮
Elisha
iOS user
This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now
Paul T
iOS user
The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.
Stefan S
iOS user
This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.
Samantha Klich
Android user
Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.
Anna
iOS user
Best app on earth! no words because it’s too good
Thomas R
iOS user
Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.
Basil
Android user
This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.
David K
iOS user
The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!
Sudenaz Ocak
Android user
In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.
Greenlight Bonnie
Android user
very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.
Rohan U
Android user
I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didn’t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as I’m sure you too will see developments.
Xander S
iOS user
THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮
Elisha
iOS user
This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now
Paul T
iOS user
jessica
@jessicaa7
Aromatic chemistry centres around benzene, a remarkably stable ring-shaped molecule that forms the backbone of countless everyday products. Understanding how benzene's unique structure makes it both incredibly stable and reactive in specific ways is crucial for grasping organic chemistry.
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Ever wondered why benzene (C₆H₆) is so special compared to other hydrocarbons? This cyclic, planar molecule has each carbon bonded to two other carbons and one hydrogen, with the remaining electron sitting in a p-orbital above and below the ring.
What makes benzene truly unique is its delocalised electron structure. Unlike what you'd expect from alternating single and double bonds, all C-C bonds are exactly the same length (139pm). This delocalisation creates extraordinary stability.
Scientists prove benzene's stability by comparing enthalpy of hydrogenation values. If benzene had three separate double bonds like cyclohexatriene, we'd expect -360 kJ/mol, but it's actually much less negative, showing benzene needs more energy to break its bonds.
Key Insight: Benzene's stability comes from delocalised electrons forming a 'ring of charge' above and below the carbon atoms.
Arenes (aromatic compounds) can be named in two ways: either as substituted benzenes (like bromobenzene) or with benzene as a phenyl functional group (like phenylamine for C₆H₅NH₂). The naming depends on which part of the molecule is more significant.
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Improve your grades
Join milions of students
By signing up you accept Terms of Service and Privacy Policy
Benzene's stability creates a problem - it's too stable to react easily! However, chemists have developed clever ways to make it react through electrophilic substitution rather than addition reactions that would destroy the stable ring.
Friedel-Crafts acylation uses a halogen carrier catalyst like AlCl₃ to create a powerful electrophile. The catalyst polarises an acyl chloride (RCOCl), forming a carbocation that's strong enough to attack benzene's electron-rich ring. Under reflux with dry ether, this produces phenylketones.
The reaction mechanism involves the delocalised electrons attacking the electrophile, temporarily breaking the ring's stability. A hydrogen is then removed, reforming the aromatic ring with the new acyl group attached.
Exam Tip: Remember that benzene undergoes substitution, not addition - this preserves the stable aromatic ring structure.
Nitration of benzene creates nitrobenzene, essential for making explosives and dyes. Concentrated nitric and sulfuric acids react to form the nitronium ion (NO₂⁺), a powerful electrophile. Keep temperatures below 55°C to avoid multiple substitutions - too hot and you'll get unwanted products!
Our AI Companion is a student-focused AI tool that offers more than just answers. Built on millions of Knowunity resources, it provides relevant information, personalised study plans, quizzes, and content directly in the chat, adapting to your individual learning journey.
You can download the app from Google Play Store and Apple App Store.
That's right! Enjoy free access to study content, connect with fellow students, and get instant help – all at your fingertips.
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Explore essential synthetic routes for aliphatic compounds in organic chemistry. This summary covers reaction pathways for alkanes, alcohols, ketones, and carboxylic acids, detailing key reagents and conditions. Ideal for OCR A Level Chemistry students seeking to master organic synthesis mechanisms.
ChemistryExplore key concepts in organic chemistry, including functional groups, IUPAC nomenclature, reaction mechanisms, and polymer chemistry. This comprehensive summary covers aromatic compounds, alkenes, aldehydes, ketones, and mass spectrometry, providing essential insights for students. Ideal for exam preparation and understanding organic synthesis, chemical reactions, and molecular structures.
ChemistryExplore key concepts in organic chemistry, including reaction mechanisms, stereochemistry, and functional groups. This comprehensive summary covers alcohols, alkenes, carboxylic acids, and more, providing insights into molecular structures and properties. Ideal for IB Chemistry HL students preparing for exams.
ChemistryExplore the chemistry of alcohols and carboxylic acids, including their structures, properties, and reactions. This summary covers homologous series, energy calculations, and the fermentation process for ethanol production. Ideal for students studying organic chemistry.
ChemistryExplore the mechanisms of electrophilic addition reactions in organic chemistry, focusing on alkenes and their derivatives. This summary covers key concepts such as carbocation formation, isomerism, and the environmental impact of various fuels, including biofuels and hydrogen. Ideal for OCR A-Level Chemistry students seeking to understand the relationship between organic reactions and fuel development.
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The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.
Stefan S
iOS user
This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.
Samantha Klich
Android user
Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.
Anna
iOS user
Best app on earth! no words because it’s too good
Thomas R
iOS user
Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.
Basil
Android user
This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.
David K
iOS user
The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!
Sudenaz Ocak
Android user
In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.
Greenlight Bonnie
Android user
very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.
Rohan U
Android user
I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didn’t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as I’m sure you too will see developments.
Xander S
iOS user
THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮
Elisha
iOS user
This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now
Paul T
iOS user
The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.
Stefan S
iOS user
This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.
Samantha Klich
Android user
Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.
Anna
iOS user
Best app on earth! no words because it’s too good
Thomas R
iOS user
Just amazing. Let's me revise 10x better, this app is a quick 10/10. I highly recommend it to anyone. I can watch and search for notes. I can save them in the subject folder. I can revise it any time when I come back. If you haven't tried this app, you're really missing out.
Basil
Android user
This app has made me feel so much more confident in my exam prep, not only through boosting my own self confidence through the features that allow you to connect with others and feel less alone, but also through the way the app itself is centred around making you feel better. It is easy to navigate, fun to use, and helpful to anyone struggling in absolutely any way.
David K
iOS user
The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!
Sudenaz Ocak
Android user
In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.
Greenlight Bonnie
Android user
very reliable app to help and grow your ideas of Maths, English and other related topics in your works. please use this app if your struggling in areas, this app is key for that. wish I'd of done a review before. and it's also free so don't worry about that.
Rohan U
Android user
I know a lot of apps use fake accounts to boost their reviews but this app deserves it all. Originally I was getting 4 in my English exams and this time I got a grade 7. I didn’t even know about this app three days until the exam and it has helped A LOT. Please actually trust me and use it as I’m sure you too will see developments.
Xander S
iOS user
THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮
Elisha
iOS user
This apps acc the goat. I find revision so boring but this app makes it so easy to organize it all and then you can ask the freeeee ai to test yourself so good and you can easily upload your own stuff. highly recommend as someone taking mocks now
Paul T
iOS user
Sociology